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sodium phosphate – Water Technology Report

Apr 27, 2015 · These include sodium phosphate, chelating agents like EDTA, and synthetic polymers. Two forms of sodium phosphate find application in low and medium pressure boilers; disodium phosphate (NaHPO4 having a 49% P2O5 content) and sodium metaphosphate (NaPO3 having a 69% P2O5 content). Both react under boiler conditions to produce orthophosphate (o-PO4).

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5-2 Recovery Boiler Water Treatment

Treatment 6Without Dispersants, Gray Mayonnaise Deposits Are In Drums Hardness – Definition 6Mainly the Calcium (Ca) and Magnesium (Mg) 6Precipitates and Forms Hardness Scale In Boiler 6Precipitation Can Result in Decreased Boiler pH 3CaSO 4 + 2Na 2HPO 4 → Ca 3(PO 4) 2 + 2Na 2SO 4 + H 2SO 4 Sulfuric Acid + Sodium Sulfate + Calcium Phosphate

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Water treatment recommendations - Power Engineering

Apr 01, 1995 · Sodium phosphate compounds are added to boiler water to control the pH and to react with any hardness compounds that might enter due to condenser leaks, demineralizer upsets, etc.

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Boiler Water Treatment - Home - Association of Water

Hartford Steam Boiler Boiler Water Treatment Phosphate compounds are common additives for boiler water treatment. Phosphate compounds react with any remaining hard water compounds to create a soft sludge that is eliminated through blowdown. Trisodium phosphate is the most common compound for lower pressure boilers. Phosphates also

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Chemical Treatment Requirements for Steam and Hot Water

Jun 12, 2017 · If boiler water solids concentrate or dry out on the boiler surface, trisodium phosphate does not precipitate or dry out as trisodium phosphate (Na 3 PO 4), but rather as a chemical composition of sodium hydrogen phosphate having the composition ratio of Na 2.8 H 0.2 PO 4. The molar ratio of sodium to phosphate is known as the congruent ratio.

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why trisodium phosphate dosing in boiler drum – CFBC

Trisodium Phosphate Uses In Boiler Water Treatment. Add proper amount of tsp chemical powder to the boiler water, it can react with calcium and magnesium salts and other substances that easy to scale and form the loose sludge suspended in the boiler water. Then it can be discharged outside through the sewage and achieve the goal of reducing the scale.

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disadvantages of trisodium phosphate dosing - CFBC Boiler

When calcium phosphate is formed in boiler water of sufficient alkalinity High-Pressure Boiler Water Treatment. The water used in high pressure steam plants is Inferred pH in Steam Plant Water Chemistry Monitoring conductivity in phosphate treated boilers. one mole of trisodium phosphate will increase boiler water pH Correcting the dosage of

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Considerations for High Pressure Boiler Chemical Treatment

case, but normally only tri and di-sodium phosphate will be required to counter normal contaminant variation in the incoming boiler feedwater. Most water treatment companies can provide blends of sodium phosphate products at various sodium to phosphate molar ratios. Figure 1: Relative corrosion of carbon steel by HCI and NaOH at 590°F (310°C).

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Program determines sodium-to-phosphate ratio in boiler water

Using of congruent phosphate as equilibrium phosphate boilers water

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Plant Service Bulletin: Boiler Water Phosphate Chemistry

Boiler Water Treatment Guidelines; Columbia Boiler Co

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Why is phosphate dosing done in a boiler? - Quora

May 01, 1992 · Abstract. This paper discusses sodium phosphate compounds, notably trisodium and disodium phosphate which have been used for years at many fossil-fired power plants for boiler water treatment. The principal purpose is to buffer the boiler water at a suitable pH while adding a compound, PO {sub 4}, which reacts with contaminants to form a non-adherent sludge.

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ENGINEERING CHEMISTRY UNIT -I WATER AND ITS TREATMENT …

In high pressure boilers, an excess of a soluble phosphate is added to the boiler water to precipitate the residual calcium ions in the form of a non-adherent precipitate of calcium phosphate and thus the scale formation is prevented. 20. Differentiate between drinking water and boiler feed water.

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The International Association for the Properties of Water

Phosphate Treatment PT Conditioning regime for drum boilers in which alkalinity is achieved by dosing tri-sodium phosphate to the boiler water Preheater A circuit in an HRSG prior to the economizer and LP drum to preheat condensate Tri-sodium phosphate TSP Na3PO4 Total Organic Carbon TOC A convenient measure of total organic components in the

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Boiler Water Treatment Guidelines; Columbia Boiler Co

Figure 1: Phosphate treatment systems used in boilers [1]. The most popular treatment for low pressure boilers (< 600 psi) is dosing of tri-sodium phosphate (TSP), it reacts with water at high temperature and gives sodium hydroxide to increase boilers water pH as shown in equation (1). 3 4 2 + → 2 4 + Na PO H O Na HPO NaOH (1)

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High-Pressure Steam Cycle and Boiler Water Treatment

ULTRAMARINESM HP BWT Program • Drew Marine pioneered the "modified phosphate-pH treatment" – Utilizes disodium orthophosphate and caustic so that no "free caustic" is generated in the boiler water – Sodium to phosphate ratio is approximately 2.75:1 and provides margin of safety for good control of the program – Went into effect in the marine industry in the 1960's and has

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Silica Analyzer | Phosphate Analyzer

Used within power plant drum-type boilers, phosphate treatment plays two important roles. First, maintaining proper alkalinity within the boiler water. Second, phosphate controls scale build-up for effective blowdown and protection against corrosion. A silica and phosphate analyzer allows the monitoring of phosphate levels to enables reliable

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BASIC WATER TREATMENT OF STEAM BOILERS

May 02, 2000 · tied up by dispersants and chelants and remain suspended in the boiler water where they can be removed by continuous surface or bottom blow down. Left improperly treated silica and iron both can form harmful deposits. ASME Phosphate Treatment Guidelines (boilers below 600 PSIG) OH-Alkalinity 100-600ppm Phosphate 30-50ppm Silica 200 - (0.25x

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Using of congruent phosphate as equilibrium phosphate

The Function of Tri sodium Phosphate dosing in Boiler water is to condition feed water to ensure that plant involved in the steam / water cycle is kept free from corrosion. Tri – sodium phosphate solution is to be dosed in Boiler Drum / HRSG Drums to maintain water PH, to minimize potential acid and caustic corrosion in the drums.

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Phosphate Hide out - BR Initiative Energy

Objective How to avoid "phosphate hide out" in the boiler drum water in power plants. Boiler Drum water treatment In order to maintain the water steam cycle chemistry in power station boilers, a numbers of chemical treatment are adopted. In the power station boilers when the unit is synchronized concentration of minerals increases in the […]

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The International Association for the Properties of Water

Phosphate Treatment PT Conditioning regime for drum boilers in which alkalinity is achieved by dosing tri-sodium phosphate to the boiler water Preheater A circuit in an HRSG prior to the economizer and LP drum to preheat condensate Tri-sodium phosphate TSP Na3PO4 Total Organic Carbon TOC A convenient measure of total organic components in the

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